One of the biggest clues, of course is weight. Plastic is often lighter than other materials. Then there's feel. Plastic tends to feel warm, while glass feels cooler to the touch. Of course, there's also close examination with a loupe and some other tests. But plastic can be a great pretender, which is one of the reasons it's been used for so many years in jewelry.
Lucite also became popular during the 1940's and 1950's because it was used for the war. The materials that were used in airplane windshields was also used to make jewelry, handbags and high heels. I remember this era quite well because my Mom's favorite outfit included a clear plastic basket handbag and a pair of clear high heels studded with rhinestone designs.
Today, all kinds of plastics, including Bakelite, are still used in making jewelry. Inexpensive plastic can be made to look like much more expensive materials or used on their own to make whimsical and beautiful designs. If you'd like to learn more about plastic jewelry, I would suggest Collecting Art Plastic Jewelry by Lee Leshner and Plastic Jewelry by Lyngerad Kelley and Nancy Schiffer.
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